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Milling

Cyclone Milll Twister TW1100

The special design of the rotary Knife , grinding cavity and grinding screen not only ensures the samples is not affected by the heat so as to guarantee the grinding effect, but also makes the cleaning quick and convenient.The TW1100 can provide very fast and convenient sample treatment, and it is suitable for various analytical techniques.

Sample type -Fibrous,soft,Dry and low fat ( up to 15% water and 10?t )

Typical samples – Granule tablets, corn ,cattle feed ,Noodles, Medicine, Beans , Tobacco, Etc.,

Features and Advantages

  • Powerful motor and high speed ensures high grinding efficiency

  • Cyclone separator can collect samples quickly

  • No cross contamination , easy to clean

  • Professional Industrial Design , long service life

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Cyclone Milll Twister TW1100 (labindia-analytical.com)


Vibratory Disc Mill 1100

VDM 1100 Vibratory Disc Mill is mainly used for sample preparation of spectral analysis. The Device is especially suitable for fast medium – Hard. Hard, brittle and Fibrous materials to analytical fineness grinding without loss. VDM 1100 Vibratory Disc Mill crush sample via pressure, impact and friction. The Quick – action clamping device makes the grinding set firmly attached onto the vibrating plate. Through transmission the vibrating plate will generate drastic three dimensional vibrating so as to produce giant impacting, frictional and grinding force on the grinding set, and such forces focus on sample to make them become powder in a very short time.

Applications

  • Ceramics and glass : oxide Ceramics ,glass

  • Building Materials : Cement, stone, Concrete ,clinker ,Raw meal etc.

  • Environmental area : Soil , paving stone , slag

  • Minerals & Metallurgy : Coal ,coke ,corundum ,ore ,slag

Standard Features of Vibratory Disc Mill 1100

  • Extremely short grinding time with quick ,loss free and reproducible grinding

  • High Final Fineness (d95 < 50>

  • Digital Speed 700 – 1500rpm , continuous Adjustable

  • Quick – action clamping device for grinding set

  • Different kinds of material of grinding sets for choice

  • Agate & Tungsten carbide recognition for automatic speed reduction ( 700& 1200 rpm)

  • Colour graphical display with single touch easy programming of parameters

  • Storage memory for 10 SOP’s with parameters

  • Wide range of grinding material for various applications ranging 50-250ml ( Hardened steel , stainless steel , Agate , Tungsten carbide, Zirconium Oxide ,steel 1.1740 for grinding without heavy metal contamination )

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Vibratory Disc Mill 1100 (labindia-analytical.com)


Vibratory Disc Mill VDM 1200

VDM 1200 Vibratory Disc Mill is mainly used for sample Preparation of spectral analysis. The device is especially suitable for fast fine grinding without loss. No matter the material is Medium – Hard, Hard, Brittle and Fibrous. The VDM 1200 grinder can perform sample preparation treatment in dry conditions namely dry grinding. Three kinds of material grinding sets are available Viz.Hardened steel, Tungsten carbide, and high manganese steel. VDM 1200 Vibratory Disc Mill crush sample via pressure, impact and friction. The quick – action clamping device makes the grinds set firmly attached onto the vibrating plate.

Applications

  • Ceramics and glass: oxide Ceramics, glass

  • Building Materials: Cement, stone, Concrete, clinker, Raw meal etc.

  • Environmental area: Soil, paving stone, slag

  • Minerals & Metallurgy: Coal, coke, corundum, ore ,slag

Standard Features of Vibratory Disc Mill VDM 1200

  • Compact floor type design saves spaces

  • Large sample processing capacity, up to 1.8kg per batch

  • High final fineness (d95<75>)

  • Safe and rapid pneumatic fastening device

  • The design of safety protection lock can guarantee safe operation

  • Grinding sets made of three different kinds of materials are available for choices

  • Unique assistance device facilitates the movement of grinding cups

  • Grinding cups of three kinds of volumes can be equipped; one to three samples can be processed for each batch

  • 2.2KW strong power motor and the grinding efficiency is 30% higher than that of similar products

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Vibratory Disc Mill VDM 1200 (labindia-analytical.com)


Vibratory Disc Mill VDM 1000 Series

VDM vibratory Disc Mill is mainly used for samples preparation of spectral analysis. This Device is especially suitable for fast Medium – Hard, Hard, Brittle and Fibrous material to analytical fineness grinding without loss. VDM Vibratory Disc Mill grinds the sample by impact and friction. The quick – action clamping device makes the grinding set firmly attached onto the vibrating plate. Through transmission, the vibrating plate will generate drastic three dimensional vibrating so as to produce giant impacting, frictional and grinding force on the grinding set , and such forces focus on samples to make them become powder in a very short time.

Standard Features of Vibratory Disc Mill VDM 1000 Series

  • Uniform sampling granularity, fast, reliable, high grinding efficiency.

  • Grinding material can be used directly without screening, fewer process, high production efficiency

  • Reasonable design: the whole sealed design, no dust pollution, conforms to environmental compliance.

  • Stable operation. low noise, reaches the safety requirements

  • Compact structure, easy maintenance, and handle

  • One to three samples can be ground at the same time

  • Grinding pot is made of especial anti-wear material and sealed well without any loss samples

  • Timer is optional for equipment.

Applications

  • Ceramics and glass : oxide Ceramics ,glass

  • Building Materials : Cement, stone, Concrete ,clinker ,Raw meal etc.

  • Environmental area : Soil , paving stone , slag

  • Minerals & Metallurgy : Coal ,coke ,corundum ,ore ,slag

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Vibratory Disc Mill VDM 1000 Series (labindia-analytical.com)


High Energy Ball Mill

LABINDIA's High Energy Ball Mill MM1600 is a multi-functional bench-top ball mill specially designed for fast preparation of ultra-fine sample with high sample throughput capable of handling 6-384 samples simultaneously in modern laboratory applications, specially for Dry, Wet and Cryogenic grinding  can process multiple small sample volumes.Grinds, Mixes, Homogenizes any kind powders and Suspensions (Hard Soft, Brittle, Elastic  Fibrous Samples types in nature) in only few seconds and grinds down to nanometer Size.

Features and advantages

  • Advanced 7” LED Colour Touchscreen design with easy to control the instrument programs and digitally adjustable grinding parameters

  • Suitable for Dry, Wet and Cryogenic grinding.

  • Applications covers Size reduction, Mixing, Homogenization, Cryogenic Grinding, Nucleic acid extraction sample pre-treatment with extremely short processing time.

  • Wide range of grinding jars and accessories for extensive applications from 1.5 to 125 ml (Stainless Steel, Zirconium oxide, Tungsten carbide, Agate, PTFE ) (1.5ml / 2ml / 5ml/ 10ml / 25ml / 35ml / 50ml / 80 ml / 125 ml)

  • Various grinding balls with construction of material (Stainless Steel, Zirconium oxide, Tungsten carbide, Agate, PTFE) (0.5,1,2,3,5,7, 0,12,15,20,25,30,40 mm)

  • Cryo Kit for cooling the grinding jars or adapter with Liquid Nitrogen

  • Designed for high sample throughput, up to 384 samples simultaneously.

  • Program setting can control the Speed, operation time, interim grinding, program storage & Cycle Times etc.

  • Storage of 20 sets of SOP’s

  • Cycle Times 1-99 (Digitally programmed)

  • The transparent window on the upper lid allows user to check the grinding status any time

  • Safety Lock Device for the upper lid ensures the motor stops running when the upper lid is opened in the grinding process for user personal safety.

  • LN2 & Water Cooling Provision (External) through Chiller

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test (labindia-analytical.com)


Micro Ball Mill MM 1100

Micro Ball Mill MM 1100 grinds and homogenizes small sample volumes quickly and efficiently by impact and friction. They are suitable for dry, wet and cryogenic grinding as well as for cell disruption for DNA/RNA recovery.

Standard Features of Micro Ball Mill MM1100

  • Size reduction, Mixing, Homogenization, Cell disruption. Dry, Wet & Cryogenic Grindings just in Sec. to sub microns.

  • Pulverization of two samples from 0.2 to 50 ml in 30 Sec. Perfect for disruption of biological cells as well as for DNA/RNA and protein extraction.

  • Integrated Advanced Touchscreen display with all digitally adjustable speed, Grinding time, interium grinding etc.

  • Powerful & quick grinding to fineness up to less than 5 µm Feed Size less than 10 mm.

  • Digitally adjustable vibrational frequency 180-110RPM Sample Volume 0.2-20 ml

  • Digitally selectable grinding time 1 Sec — 100 min

  • Wide range of grinding jars 2-50m1 (Stainless Steel, Agate, Zirconium Oxide, Tungsten Carbide & PTFE) specially designed with 'Easy-Clamping System'

  • Transparent window on the upper lid to check the grinding status.

  • Safety Lock Device for the upper lid ensures the motor stops running when the upper lid is opened in the grinding process for user personal safety

  • Cryo Kit for cooling the grinding jars or adapter with Liquid Nitrogen.

  • Adapters for Disruption of Biological Cells reaction vials up to 96 and adapters can be placed into Liquid nitrogen directly with various reaction vials.

  • Bead Dispenser suitable for 96- hole deep well plate with 3mm & 5mm sizes of choice.

  • Storable memory of 9 SOPs.

  • Complete range of grinding balls with all MOCs

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Top Ball Mill Grinder Machine- Lab Micro Ball Mill MM 1100 (labindia-analytical.com)


Cryogenic Ball Mill CM1100

Cryo Grinder CM1100 is used to process samples with toughness and thermal sensitivity. Such samples are difficult to be ground and crushed at room temperature, CM1100 chills the sample in liquid nitrogen and pulverize them with a magnetically driven impactor and good results can be achieved. CM 1100 is used in applications such as rubber, plastic, food, mineral, animal and plant tissue analysis, drug, biochemical DNA detection, cell disruption and other fields.

Standard Features of Cryogenic Ball Mill CM1100

  • Designed for powerful cryogenic grinding applications, in order to maintain the samples and biological information, the grinding jar is continuously cooled with Liquid Nitrogen @ -196 °C and pulverize with a magnetically driven impactor.

  • Size reduction, Mixing, Homogenization, Cell disruption. Cryogenic Grinding, Dry or Wet @ Ambient temp. Modes of operation

  • Integrated Advanced Touchscreen display with all digitally adjustable impact frequency, pre-cooling time, impact grinding time, cycle grinding times etc..

  • Powerful & quick grinding to fineness up to less than 5 µm Feed Size less than 10 mm.

  • Digitally adjustable impact frequency 5-15Hz

  • Batch Capacity 0.1-100g

  • Typical grinding time 4.5 / 2 min (Cooling / Grinding)

  • Pre-Cooling Chamber 200 ml & Grinding Chamber 200 ml Manual / Auto Liquid

  • Nitrogen filling option.

  • Grinding jars 4 Groups jars 3m1/4 Jars of 20m1, one Jar of 100 / 200m1

  • When the liquid nitrogen level is lower than the set value, the liquid sensor will alarm and automatically, replenish the liquid nitrogen; and the instrument stops running to protect the electromagnetic coil from damage.

  • Instrument operates only when cover is closed and locked

  • Complete range of grinding balls with all MOCs

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Finest Cryogenic Ball Mill Grinding Machine| Labindia Analytical (labindia-analytical.com)


Planetary Ball Mill BM 1100+ (1 Grinding Station)

Planetary Ball Mill BM 1100+ can not only perform mixing and grinding, but also meet the requirements of colloid grinding. In addition, its giant energy input can meet the technical requirements of preparing alloy with mechanical methods. BM 1100+ can be used for rapid fine crushing of soft, hard, brittle and fibrous material to end fineness <1um> BM 1100+ is used mainly in applications like Plant, cement clinker, concrete, compost, paints and varnishes, charcoal, hair, catalysts, chemicals, alloys, bones, metal oxides, iron ore, ceramics, polymers, bentonites, pigments etc.

Standard Features of Planetary Ball Mill BM 1100+

  • Pulverizing, Mixing, Homogenizing, Colloidal milling, Mechanical alloying.

  • One Grinding Platform.

  • Integrated LED 7" Touch Display with all digitally adjustable speed, Grinding time, Holding/Pass time, Interval operation

  • Powerful & quick grinding to nano fineness up to  less than 0.1µm Feed Size less than 10mm

  • Two different grinding Models (Dry/Wet).

  • Digitally adjustable sun wheel speed 100-65Orpm with speed ratio 1:-2 & effective sun wheel diameter 260mm Digitally selectable grinding time 0-999min (Cycle times 01-99), Pass / Holding time 0-99 min & Interval operation in reverse direction.

  • 6 kinds of grinding jars in material for contamination free grinding from 12-500 ml (Stainless Steel, Agate, Zirconium Oxide, tungsten Carbide & Sintered Aluminum Oxide).

  • The grinding jars are marked with capacity and materials are marked on the grinding jars, which is easy to distinguish from others.

  • Storable memory of 10 SOPs.

  • Automatic ventilation system for cooling the grinding jar.

  • Built-In High power fans for auto effective cooling for motors during Grinding.

  • Maintenance free Drive guarantees to maintain constant speed in continuous operation for long time operation or under maximum overload.

  • Intelligent security lock for safety.

  • Multi-Safety Design of Grinding Jars with Gas Tight, Dust- Proof & Safe Operation during Colloid Grinding & can be sealed in Colloid Grinding (Wet Grinding) to ensure Over- Pressure gas not easily escape.

  • Optional Pressure and temperature measuring system. Complete range of grinding balls with all MOCs

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Top Planetary Ball Mill Manufacturers For Laboratory In India. (labindia-analytical.com)


Planetary Ball Mill BM 1400+ (4 Grinding Stations)

Planetary Ball Mill BM 1400+can not only perform mixing and grinding, but also meet the requirements of colloid grinding. In addition, its giant energy input can meet the technical requirements of preparing alloy with mechanical methods. BM 1400+ can be used for rapid fine crushing of soft, hard, brittle and fibrous material to end fineness <1um> BM 1400+ is used mainly in applications like Plant, cement clinker, concrete, compost, paints and varnishes, charcoal, hair, catalysts, chemicals, alloys, bones, metal oxides, iron ore, ceramics, polymers, bentonites, pigments etc

Standard Features of Planetary Ball Mill BM 1400+

  • Pulverizing, Mixing, Homogenizing, Colloidal milling, Mechanical alloying Up to 4 (With 4 grinding platforms can process 2, 4, 8 samples simultaneously)

  • Integrated 7" Touch Display with all digitally adjustable speed, Grinding time, Holding/Pass time, Interval operation etc.

  • Powerful & quick grinding to Nano fineness up to less than 0.1 µm

  • Two different grinding Models (Dry / Wet)

  • Digitally adjustable sun wheel speed 30-400rpm with speed ratio 1: 2.2 / (Upgradable (-3.5) & effective sun wheel diameter 360mm

  • Digitally selectable grinding time 0-999min (Cycle times 01-99) Pass / Holding time 0-99 min & Interval operation in reverse direction.

  • 6 kinds of grinding jars in material for contamination free grinding from 12-500 ml (Stainless Steel, Agate, Zirconium Oxide, Tungsten Carbide & Sintered Aluminum Oxide)

  • The grinding jars are marked with capacity and materials are marked on the grinding jars, which is easy to distinguish from others.

  • Storable memory of 10 SOPs.

  • Automatic ventilation system for cooling the grinding jar Built-In High power fans for auto effective cooling for motors during Grinding

  • Maintenance free Drive guarantees to maintain constant speed in continuous operation for long time operation or under maximum overload

  • Intelligent security lock for safety

  • Multi-Safety Design of Grinding Jars with Gas Tight, Dust- Proof & Safe Operation during Colloid Grinding & Can be sealed in Colloid Grinding (Wet Grinding) to ensure Over- Pressure gas not easily escape.

  • Optional Pressure and temperature measuring system

  • Feed Size less than 15 mm

  • Complete range of grinding balls with all MOCs

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Versatile Planetary Ball Mill | Upto 4 Grinding Stations (labindia-analytical.com)


Planetary Ball Mill BM 1200+

The vertical Laboratory Planetary Ball Mill is a device of high tech materials mixing, fine grinding, sample making, new product development and small batch production. This planetary ball mill model owns small volume and high efficiency, low noise and functional features which is an ideal equipment for R&D institution, university, enterprises laboratory to get samples (each experiment can get four samples at the same time). It gets powder samples under the vacuum state when equipped with vacuum ball mill tank.The planetary ball mill is widely used in many fields of geology, mine, metallurgy, electric industry,Construction, ceramics, chemicals, light industry, medicine, environmental protection etc.

Standard Features of Planetary Ball Mill BM 1200+

  • Stable revolving speed of the gear transmission ensures the consistency and repeatability of the experiment.

  • Planetary movement principle is adopted in the machine, which has high speed, large energy, high efficiency, small granularity.

  • Four powder samples from different sizes and different materials can be produced at one time.

  • The machine is controlled by frequency converter, you may choose ideal rotating speed according to expected experimental result. The converter is equipped with device of under voltage and over-current to protect the motor.

  • The planetary ball mill has functions of timing power off, self-timing forward and reversal rotating. You may choose freely any operation modes of one-way direction, alternation, succession, time setting according to experimental needs, so as to improve efficiency of grinding.

  • Technical features of BM1200+ series Ball Mill: Low center of gravity, stable performance, compact structure, easy operation, reliable safety, lower noise, small loss.

  • Safety switch is installed on the machine to prevent safety accident if the safety cover is opened while machine is running.

  • Speed ratio- selectable 1:-2/1:-2.5/1:-3

  • Programme parameters can be set through standard lcd display or optional lcd colour touch screen.

  • Four jar grinding system - selection from 50ml- 4 liters depending on the selection of the model.

  • Grinding jars n balls available in 8 MOC options.

  • Noise level is less than 60db.

  • Feed size of <= 10mm and final fineness upto 1 micrometer and with colloidal grinding 100 nano meter.

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Planetary Ball Mill BM 1200+ Top Quality Grinder Machine. (labindia-analytical.com)


Hammer Mill HM 1100

Hammer Mill 1100 process samples by impacting effects which suitable for brittle mid- hard samples preparation. Also, it could process large batches of coarse and fine grinding, widely used in power plants and sample preparation labs for coal quality analysis by its easy handling, efficiency, and accuracy, less residual in mill chamber as well. Samples are fed into the center of mill chamber through patent feeding hopper, then it impacted with cross beater rotor moving at high speed and frequency to reduce particle size. Once the particle size is less than sieve holes, it will fall into collecting pan. Massive air will be absorbed by the rotor through feeding tunnel which accelerated reduced particle leave mill chamber.

Standard Features of Hammer Mill HM 1100

  • Electric Braking.

  • Bench- top, easy handling, saving space.

  • Auto feeding system, reduce operational error and contamination.

  • Rotors and Bottom sieves separating easily convenient to clean Mill chamber.

  • Controllable reduced particle size from 0.12mm to 10mm by bottom sieves diameters.

  • High frequency and high rotate speed motor (10000rpm) fulfilled efficiency milling and less residual in Mill chamber..

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Hammer Mill HM 1100 Machine at Best Price in India- Get Quote (labindia-analytical.com)


Planetary Ball Mills BM 1500+ Series

Vertical Laboratory Planetary Ball Mill has four ball grinding jars installed on one turntable. When the turntable rotates, the jar axis makes planetary movements, the balls and samples inside the jars are impacted strongly in high speed movement, and samples are eventually ground into powder. Various kinds of different materials can be ground by the mill with dry or wet method.  This planetary ball mill model owns small volume and high efficiency, low noise and functional features which is an ideal equipment for R&D institution, university, enterprises laboratory to get samples (each experiment can get four samples at the same time). It gets powder samples under the vacuum state when equipped with vacuum ball mill jar.

Applications

The planetary ball mill is widely used in many fields of geology, mine, metallurgy, electric industry, Construction, ceramics, chemicals, light industry, medicine, environmental protection etc.

Standard Features of Vertical Planetary Ball Mill BM1500+ Series

  • Stable revolving speed of the gear transmission ensures the consistency and repeatability of the experiment.

  • Planetary movement principle is adopted in the machine, which has high speed, large energy, high efficiency, small Granularity

  • Four powder samples from different sizes and different materials can be produced at one time.

  • The machine is controlled by frequency converter; you may choose ideal rotating speed according to expected experimental result. The converter is equipped with device of under voltage and over-current to protect the motor.

  • The planetary ball mill has integrated 5” Colour Touch Screen and all the functions of timing power off, self-timing forward and reversal rotating. You may choose freely any operation modes of one-way direction, alternation, succession, time setting according to experimental needs, so as to improve efficiency of grinding.

  • Technical features: Low centre of gravity, stable performance, compact structure, easy operation, reliable safety, lower noise, small loss.

  • Safety switch is installed on the machine to prevent safety accident if the safety cover is opened while machine is running.

Visit the LabIndia website for more information:

Planetary Milling Machine Best Grinding Machine in India (labindia-analytical.com)


Planetary Ball Mill BM1150+ (Two Grinding Stations)

LABINDIA Planetary Ball Mill BM1150+ (Two Grinding Stations) is suitable for grinding (Dry / Wet) and mixing some soft, hard, brittle and fibrous samples, which are used wherever the highest degree of fineness as customer required, as well as the grinding result is reproducible. Apart from the classical mixing and size reduction processes, the mills also meet all the technical requirements for colloidal grinding.

Planetary Ball Mills are used wherever the highest degree of fineness and meet all the technical requirements for colloidal grinding and have the energy input necessary for mechanical alloying Processes.

Features and Advantages

  • Two Grinding Station platform (12-250 ml Jar Sizes)

  • Advanced 7” LED Colour Industrial Touchscreen design with easy to control the instrument programs and digitally adjustable grinding parameters

  • Dry & Wet grinding Modes.

  • Powerful and Quick Grinding to Nano fineness with Comfortable operation and easy cleaning and Suitable for long-term and continuous operation

  • Automatic direction reversal to avoid agglomerations

  • Wide range of grinding jars and accessories for extensive applications from 12 to 250 ml (Stainless Steel, Zirconium oxide, Tungsten carbide, Agate, Sintered Aluminum Oxide, Sintered Oxide)

  • Various grinding balls with construction of material (Stainless Steel, Zirconium oxide, Tungsten carbide, Agate, Sintered Aluminum Oxide, Sintered Oxide, PTFE) (0.5,1,2,3,5,7, 0,12,15,20,25,30,40 mm)

  • Program setting can control the Speed, operation time, interim grinding with reverse direction, program storage & Cycle Times etc.

  • Storage of 10 sets of SOP’s

  • Cycle Times 1-99 (Digitally programmed)

  • Grinding chamber automatic ventilation system for cooling the grinding jar

  • Efficient and Maintenance free Drive guarantees to maintain constant speed in continuous operation for long time operation or under maximum overload

  • Built-In High power fans automatically provides effective cooling for motors during Grinding

  • Built in technology adoption for Vibration free running during grinding process at high RPM

  • ISO, CE & IP30 certified

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LABINDIA Planetary Ball Mill BM1150+ (Two Grinding Stations) (labindia-analytical.com)


Automatic Proximate Analyzer

It is applicable in the industry such as electrical power, coal, commerce inspection, environment protection, metallurgy, papermaking, petrochemical, earth probe and the research institute or quality inspecting organization to test the content of air-dry basis moisture, ash, LOI, and Volatile Matter in the coal. The instrument can also automatically calculate Calorific Value and the content of fixed carbon and hydrogen in the samples.

The LPA-4000 with integrated balance combines drying, ashing and weighing processes. This improves the efficiency, precision and provides high sample throughput.

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Automatic Proximate Analyzer (labindia-analytical.com)


Pulverizer (Disc Mill) DM 1100

The samples are grinded via the pressure and frictional force generated between a rotating disc and another fixed disc. After the sample enters into grinding chamber, the progressively arranged teeth of the grinding disc first subject the sample to preliminary crushing, centrifugal force then moves it to the outer regions of the grinding discs where fine grinding takes place. The ground sample falls into the sample receiver via the gap of the grinding discs.

Features and Advantages

  • Simple operation, easy cleaning

  • The sample feed size up to 20mm

  • Large processing capacity of samples

  • The gap of grinding discs can be adjusted continuously

  • Efficient sample treatment, extreme size reduction can be reached in a short time.Grinding discs made of various materials are available for selection and wear-resistant. Dust discharge connector design can prevent sample powders from polluting environment.

  • Disc Gap adjustment can be digitally displayed

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Pulverizer (Disc Milll) DM 1100 (labindia-analytical.com)

About Us

LabDynamics supplies quality laboratory equipment, consumables, analytical training courses and service and validation support to customers in South Africa and Southern Africa. We are a level 4 BEE contributor.

Contact Details

Tel: +27 660 1745
Fax: +27 866 720 980 
Gerry Cell:  +27 83 415 9987
Lynette Cell: +27 82 498 1111
E-Mail:  sales@labdynamics.co.za

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Rant and Dal
Krugersdorp
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South Africa